Try connecting using WPS. Both the BT Hub and Paperwhite support WPS and you will not need to enter the encryption key (the password it is asking for).
I have an older Kindle and IIRC you just tap the network SSID you want to connect to and when it asks for the password it also gives you a "WPS" option. Tap WPS and then press the WPS button on your hub. You should then be connected after a few seconds.
Note: There is a timeout on the hub for WPS so make sure that you press the WPS button on the hub within one minute or so of tapping WPS on the Kindle.
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